Even that super achieving, highly organized CEO will put off a task that really needs to get done. The difference between those people and the rest of us is that for the them, pprocratination is a rare event. They have what psychologists refer to as high conscientiousness. They will self-correct.
There are chronic procrastinators; people who put off all sorts of important tasks, both professional and personal. For them, professional help is necessary to help resolve what is, or will become, a debilitating habit.